Original Synthesis of Fluorenyl Alcohol Derivatives by Reductive Dehalogenation Initiated by TDAE

We report here a novel and easy-to-handle reductive dehalogenation of 9-bromofluorene in the presence of arylaldehydes and dicarbonyl derivatives to give the corresponding fluorenyl alcohol derivatives and Darzens epoxides as by-products in tetrakis(dimethylamino)ethylene (TDAE) reaction conditions....

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Bibliographic Details
Main Authors: Alain Gamal Giuglio-Tonolo, Thierry Terme, Patrice Vanelle
Format: Article
Language:English
Published: MDPI AG 2016-10-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/21/10/1408