Orientation of Chiral Schiff Base Metal Complexes Involving Azo-Groups for Induced CD on Gold Nanoparticles by Polarized UV Light Irradiation

Orientation of Chiral Schiff Base Metal Complexes Involving Azo-Groups for Induced CD on Gold Nanoparticles by Polarized UV Light Irradiation

In this study, we report the synthesis, characterization, and chiroptical properties of azo-group-containing chiral salen type Schiff base Ni(II), Cu(II), and Zn(II) complexes absorbed on gold nanoparticles (AuNPs) of 10 nm diameters. Induced circular dichroism (CD) around the plasmon region from th...

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Bibliographic Details
Main Authors: Nobumitsu Sunaga, Tomoyuki Haraguchi, Takashiro Akitsu
Format: Article
Language:English
Published: MDPI AG 2019-09-01
Series:Symmetry
Subjects:
chirality
azobenzene
photo-isomerization
Weigert effect
Schiff base complexes
gold nanoparticles
time-dependent density functional theory (TD-DFT)
Online Access:https://www.mdpi.com/2073-8994/11/9/1094

Internet

https://www.mdpi.com/2073-8994/11/9/1094

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