Crystal structure of tris[μ2-bis(diphenylphosphanyl)methane-κ2P:P′]di-μ3-bromido-trisilver(I) bromide–N,N′-phenylthiourea (1/1)

Crystal structure of tris[μ2-bis(diphenylphosphanyl)methane-κ2P:P′]di-μ3-bromido-trisilver(I) bromide–N,N′-phenylthiourea (1/1)

The title complex, [Ag3Br2(C25H22P2)3]Br·C7H8N2S, comprises a trinuclear [Ag3Br2(C25H22P2)3]+ unit, a Br− anion and one N,N′-dimethylthiourea molecule (ptu). Three AgI ions are linked via two μ3-bridging Br atoms, leading to a distorted triangular bipyramid with an Ag...Ag separation range of 3.1046...

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Bibliographic Details
Main Authors: Arunpatcha Nimthong-Roldán, Yupa Wattanakanjana, Jintana Rodkeaw
Format: Article
Language:English
Published: International Union of Crystallography 2015-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
silver complex
N,N′-phenylthiourea
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015005150

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http://scripts.iucr.org/cgi-bin/paper?S2056989015005150

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