Investigation of nitro–nitrito photoisomerization: crystal structure of trans-chloridonitro(1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)cobalt(III) chloride
The reaction cavity of the nitro group in the crystal of the title compound, [CoCl(NO2)(C10H24N4)]Cl, (I), was investigated to confirm that it offers sufficient free space for linkage isomerization to occur in accordance with the observed photochemical reactivity. The complex cation has crystallogra...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2018-12-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S205698901801678X |