Vitamin B12-catalyzed synthesis of some peracetylated alkyl b-D-xylopyranosides

The vitamin B12-catalyzed glycosylation reaction of brominated b-D-xylose peracetate with alkanols ROH (C1-C8) has been studied. The catalytically active species in this reaction was cob(I)alamin, obtained by chemical reduction of Vitamin B12 with NaBH4 (Co(III) to Co(I)). The reaction was carried o...

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Bibliographic Details
Main Authors: LJILJANA STEVANOVIC, ZORICA D. PETROVIC, DEJAN ANDJELKOVIC
Format: Article
Language:English
Published: Serbian Chemical Society 2003-10-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.shd.org.yu/HtDocs/SHD/Vol68/No10/V68-No10-04.pdf