Crystal structure of catena-poly[[[diaqua[1,2-bis(pyridin-4-yl)ethene]{4-[2-(pyridin-4-yl)ethenyl]pyridinium}gold(I)iron(II)]-di-μ-cyanido] bis[dicyanidogold(I)] 1,2-bis(pyridin-4-yl)ethene dihydrate]

Crystal structure of catena-poly[[[diaqua[1,2-bis(pyridin-4-yl)ethene]{4-[2-(pyridin-4-yl)ethenyl]pyridinium}gold(I)iron(II)]-di-μ-cyanido] bis[dicyanidogold(I)] 1,2-bis(pyridin-4-yl)ethene dihydrate]

In the title compound [Fe(bpe)(Hbpe)Au(CN)2][Au(CN)2]2·bpe·2H2O}n [where bpe = 1,2-bis(pyridin-4-yl)ethene, C12H10N2], the FeII ion is coordinated in a distorted octahedral [FeN4O2] environment by two dicyanoaurate anions, two water molecules and two partially protonated 1,2-di(4-pyridyl)ethylene mo...

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Bibliographic Details
Main Authors: Sofiia V. Partsevska, Dina D. Naumova, Igor P. Matushko, Sergiu Shova, Il'ya A. Gural'skiy
Format: Article
Language:English
Published: International Union of Crystallography 2020-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
polymeric complex
iron(ii) complex
dicyanoaurate
aurophilic interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989020006738

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http://scripts.iucr.org/cgi-bin/paper?S2056989020006738

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