Unexpected polymerization mechanism of dilignol in the lignin growing

Lignin is an essential component of higher plants, which is built by the enzymatic dehydrogenative polymerization of monolignols. First, monolignol is enzymatically oxidized to produce the phenoxy radical, which can form resonance hybrids. Two radical resonant hybrids are coupled with each other to...

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Bibliographic Details
Main Authors: Yasuyuki Matsushita, Yuto Oyabu, Dan Aoki, Kazuhiko Fukushima
Format: Article
Language:English
Published: The Royal Society 2019-07-01
Series:Royal Society Open Science
Subjects:
Online Access:https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.190445