Thermal Reactivity of Neutral and Oxidized Ferrocenyl-Substituted Enediynes

Thermal Reactivity of Neutral and Oxidized Ferrocenyl-Substituted Enediynes

The coupling of two equivalents of ethynylferrocene (2) with one equivalent of 1,2-diiodocyclohexene (1) and 1,2-diiodobenzene (4) using Sonogashira cross-coupling conditions led to 1,2-bis(ferrocenylethynyl)cyclohexene (3) and 1,2-bis(ferrocenylethy­nyl)benzene (5), respectively. At high temperatur...

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Bibliographic Details
Main Authors: Mehmet Emin Cinar, Guido Morbach, Michael Schmittel
Format: Article
Language:English
Published: MDPI AG 2014-11-01
Series:Molecules
Subjects:
enediyne
ferrocene
thermal electron transfer
monocation
DFT
differential scanning calorimetry (DSC)
Online Access:http://www.mdpi.com/1420-3049/19/11/18399

Internet

http://www.mdpi.com/1420-3049/19/11/18399

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