A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene

A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene

A novel complex featuring a mesoionic carbene [Fe2(CO)5(trz)(μ-pdt)] (1) (trz = 1-phenyl-l,3-methyl,4-butyl-1,2,3-triazol-5-ylidene), was synthesized and spectroscopically and structurally characterized. The reductive behaviour of this compound in the presence and in the absence of acid (CH3CO2H) wa...

Full description

Bibliographic Details
Main Authors: Andrea Mele, Simone Bertini, Martin Albrecht, Catherine Elleouet, Francois Pétillon, Philipp Schollhammer
Format: Article
Language:deu
Published: Swiss Chemical Society 2020-06-01
Series:CHIMIA
Subjects:
bioinspired model
diiron complex
hydrogenase
mesoionic carbene
proton reductions
Online Access:https://www.ingentaconnect.com/contentone/scs/chimia/2020/00000074/00000006/art00010

Internet

https://www.ingentaconnect.com/contentone/scs/chimia/2020/00000074/00000006/art00010

Similar Items