A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene

A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene

A novel complex featuring a mesoionic carbene [Fe2(CO)5(trz)(μ-pdt)] (1) (trz = 1-phenyl-l,3-methyl,4-butyl-1,2,3-triazol-5-ylidene), was synthesized and spectroscopically and structurally characterized. The reductive behaviour of this compound in the presence and in the absence of acid (CH3CO2H) wa...

Full description

Bibliographic Details
Main Authors: Andrea Mele, Simone Bertini, Martin Albrecht, Catherine Elleouet, Francois Pétillon, Philipp Schollhammer
Format: Article
Language:deu
Published: Swiss Chemical Society 2020-06-01
Series:CHIMIA
Subjects:
bioinspired model
diiron complex
hydrogenase
mesoionic carbene
proton reductions
Online Access:https://www.ingentaconnect.com/contentone/scs/chimia/2020/00000074/00000006/art00010
id doaj-3b494f85b5704f1d8b1ea53cbc20d677
record_format Article
spelling doaj-3b494f85b5704f1d8b1ea53cbc20d6772020-11-25T03:07:20ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24242020-06-0174649950310.2533/chimia.2020.499A Diiron Hydrogenase Mimic Featuring a 1,2,3-TriazolylideneAndrea Mele0Simone Bertini1Martin Albrecht2Catherine Elleouet3Francois Pétillon4Philipp Schollhammer5Laboratoire de Chimie, Electrochimie Moléculaires et Chimie Analytique, UMR 6521 CNRS - Université de Bretagne Occidentale, CS 93837 - 6 Avenue Le Gorgeu, 29238 BREST Cedex 3 - FranceDepartement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, CH-3012 Bern, SwitzerlandDepartement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, CH-3012 Bern, SwitzerlandLaboratoire de Chimie, Electrochimie Moléculaires et Chimie Analytique, UMR 6521 CNRS - Université de Bretagne Occidentale, CS 93837 - 6 Avenue Le Gorgeu, 29238 BREST Cedex 3 - FranceLaboratoire de Chimie, Electrochimie Moléculaires et Chimie Analytique, UMR 6521 CNRS - Université de Bretagne Occidentale, CS 93837 - 6 Avenue Le Gorgeu, 29238 BREST Cedex 3 - FranceLaboratoire de Chimie, Electrochimie Moléculaires et Chimie Analytique, UMR 6521 CNRS - Université de Bretagne Occidentale, CS 93837 - 6 Avenue Le Gorgeu, 29238 BREST Cedex 3 - FranceA novel complex featuring a mesoionic carbene [Fe2(CO)5(trz)(μ-pdt)] (1) (trz = 1-phenyl-l,3-methyl,4-butyl-1,2,3-triazol-5-ylidene), was synthesized and spectroscopically and structurally characterized. The reductive behaviour of this compound in the presence and in the absence of acid (CH3CO2H) was examined by cyclic voltammetry (CV) that revealed the lack of efficient activity towards proton reduction.https://www.ingentaconnect.com/contentone/scs/chimia/2020/00000074/00000006/art00010bioinspired modeldiiron complexhydrogenasemesoionic carbeneproton reductions
collection DOAJ
language deu
format Article
sources DOAJ
author Andrea Mele
Simone Bertini
Martin Albrecht
Catherine Elleouet
Francois Pétillon
Philipp Schollhammer
spellingShingle Andrea Mele
Simone Bertini
Martin Albrecht
Catherine Elleouet
Francois Pétillon
Philipp Schollhammer
A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene
CHIMIA
bioinspired model
diiron complex
hydrogenase
mesoionic carbene
proton reductions
author_facet Andrea Mele
Simone Bertini
Martin Albrecht
Catherine Elleouet
Francois Pétillon
Philipp Schollhammer
author_sort Andrea Mele
title A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene
title_short A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene
title_full A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene
title_fullStr A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene
title_full_unstemmed A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene
title_sort diiron hydrogenase mimic featuring a 1,2,3-triazolylidene
publisher Swiss Chemical Society
series CHIMIA
issn 0009-4293
2673-2424
publishDate 2020-06-01
description A novel complex featuring a mesoionic carbene [Fe2(CO)5(trz)(μ-pdt)] (1) (trz = 1-phenyl-l,3-methyl,4-butyl-1,2,3-triazol-5-ylidene), was synthesized and spectroscopically and structurally characterized. The reductive behaviour of this compound in the presence and in the absence of acid (CH3CO2H) was examined by cyclic voltammetry (CV) that revealed the lack of efficient activity towards proton reduction.
topic bioinspired model
diiron complex
hydrogenase
mesoionic carbene
proton reductions
url https://www.ingentaconnect.com/contentone/scs/chimia/2020/00000074/00000006/art00010
work_keys_str_mv AT andreamele adiironhydrogenasemimicfeaturinga123triazolylidene
AT simonebertini adiironhydrogenasemimicfeaturinga123triazolylidene
AT martinalbrecht adiironhydrogenasemimicfeaturinga123triazolylidene
AT catherineelleouet adiironhydrogenasemimicfeaturinga123triazolylidene
AT francoispetillon adiironhydrogenasemimicfeaturinga123triazolylidene
AT philippschollhammer adiironhydrogenasemimicfeaturinga123triazolylidene
AT andreamele diironhydrogenasemimicfeaturinga123triazolylidene
AT simonebertini diironhydrogenasemimicfeaturinga123triazolylidene
AT martinalbrecht diironhydrogenasemimicfeaturinga123triazolylidene
AT catherineelleouet diironhydrogenasemimicfeaturinga123triazolylidene
AT francoispetillon diironhydrogenasemimicfeaturinga123triazolylidene
AT philippschollhammer diironhydrogenasemimicfeaturinga123triazolylidene
_version_ 1724671083657822208

Similar Items