Reduction of the Diazo Functionality of α-Diazocarbonyl Compounds into a Methylene Group by NH<sub>3</sub>BH<sub>3 </sub>or NaBH<sub>4</sub> Catalyzed by Au Nanoparticles

Reduction of the Diazo Functionality of α-Diazocarbonyl Compounds into a Methylene Group by NH<sub>3</sub>BH<sub>3 </sub>or NaBH<sub>4</sub> Catalyzed by Au Nanoparticles

Supported Au nanoparticles on TiO<sub>2</sub> (1 mol%) are capable of catalyzing the reduction of the carbene-like diazo functionality of α-diazocarbonyl compounds into a methylene group [C=(N<sub>2</sub>) → CH<sub>2</sub>] by NH<sub>3</sub>BH<sub&g...

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Bibliographic Details
Main Authors: Marios Kidonakis, Manolis Stratakis
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Nanomaterials
Subjects:
α-diazocarbonyl compounds
transfer hydrogenation
boron hydrides
heterogeneous catalysis
supported Au nanoparticles
Online Access:https://www.mdpi.com/2079-4991/11/1/248

Internet

https://www.mdpi.com/2079-4991/11/1/248

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