Synthesis of 2-((2-(Benzo[d]oxazol-2-yl)-2<i>H</i>-imidazol-4-yl)amino)-phenols from 2-((5<i>H</i>-1,2,3-Dithiazol-5-ylidene)amino)phenols through Unprecedented Formation of Imidazole Ring from Two Methanimino Groups

Synthesis of 2-((2-(Benzo[d]oxazol-2-yl)-2<i>H</i>-imidazol-4-yl)amino)-phenols from 2-((5<i>H</i>-1,2,3-Dithiazol-5-ylidene)amino)phenols through Unprecedented Formation of Imidazole Ring from Two Methanimino Groups

A new synthetic pathway to four substituted imidazoles from readily available 2-((4-aryl(thienyl)-5<i>H</i>-1,2,3-dithiazol-5-ylidene)amino)phenols has been developed. Benzo[<i>d</i>]oxazol-2-yl(aryl(thienyl))methanimines were proved as key intermediates in their synthesis. T...

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Bibliographic Details
Main Authors: Ilia V. Baranovsky, Lidia S. Konstantinova, Mikhail A. Tolmachev, Vadim V. Popov, Konstantin A. Lyssenko, Oleg A. Rakitin
Format: Article
Language:English
Published: MDPI AG 2020-08-01
Series:Molecules
Subjects:
sulfur-nitrogen heterocycles
5-Arylimino-1,2,3-dithiazoles
four substituted 2<i>H</i>-imidazol-4-amines
X-ray analysis
thermolysis
Online Access:https://www.mdpi.com/1420-3049/25/17/3768

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https://www.mdpi.com/1420-3049/25/17/3768

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