Bond formation dynamics of dicyanoaurate in the first excited singlet state
Time-resolved fluorescence of [Au(CN)2−]3 in water reveals a coherent vibration of 74 cm-1. A massive non-Condon effect, proved unambiguously by time-resolved fluorescence spectra, demonstrates that the wave packet motion arises from the coherent bond formation.
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
EDP Sciences
2019-01-01
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| Series: | EPJ Web of Conferences |
| Online Access: | https://www.epj-conferences.org/articles/epjconf/pdf/2019/10/epjconf_up2019_09021.pdf |