A Robust Pyridyl-NHC-Ligated Rhenium Photocatalyst for CO2 Reduction in the Presence of Water and Oxygen

A Robust Pyridyl-NHC-Ligated Rhenium Photocatalyst for CO2 Reduction in the Presence of Water and Oxygen

Re(pyNHC-PhCF3)(CO)3Br is a highly active photocatalyst for CO2 reduction. The PhCF3 derivative was previously empirically shown to be a robust catalyst. Here, the role of the PhCF3 group is probed computationally and the robust nature of this catalyst is analyzed with regard to the presence of wate...

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Bibliographic Details
Main Authors: Casey A. Carpenter, Phillip Brogdon, Louis E. McNamara, Gregory S. Tschumper, Nathan I. Hammer, Jared H. Delcamp
Format: Article
Language:English
Published: MDPI AG 2018-01-01
Series:Inorganics
Subjects:
CO2 reduction
photocatalysis
NHC-ligated complexes
Online Access:http://www.mdpi.com/2304-6740/6/1/22

Internet

http://www.mdpi.com/2304-6740/6/1/22

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