NMR and EPR Study of Homolysis of Diastereomeric Alkoxyamines

NMR and EPR Study of Homolysis of Diastereomeric Alkoxyamines

Three alkoxyamines based on imidazoline radicals with a pyridine functional group—potential initiators of nitroxide-mediated, controlled radical polymerization—were synthesized. Electron Paramagnetic Resonance (EPR) measurements reveal biexponential kinetics for the thermolysis for diastereomeric al...

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Bibliographic Details
Main Authors: Sergey Cherkasov, Dmitriy Parkhomenko, Alexander Genaev, Georgii Salnikov, Mariya Edeleva, Denis Morozov, Tatyana Rybalova, Igor Kirilyuk, Sylvain R. A. Marque, Elena Bagryanskaya
Format: Article
Language:English
Published: MDPI AG 2020-11-01
Series:Molecules
Subjects:
nitroxide
alkoxyamine
nitroxide mediated polymerization
kinetics
scavenger
imidazoline radical
Online Access:https://www.mdpi.com/1420-3049/25/21/5080

Internet

https://www.mdpi.com/1420-3049/25/21/5080

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