Intramolecularly coordinated diarylindium and diarylthallium chlorides [(8-Me2NC10H6)2E]Cl (E=In, Tl) with essentially ionic structures

The reaction of 8-Me2NC10H6Li·Et2O with InCl3 and TlCl, respectively, followed by work-up under aerobic conditions, provided the intramolecularly coordinated diarylelement chlorides [(8-Me2NC10H6)2E]Cl (1, E=In; 2, E=Tl) in reasonable yields. Single crystal X-ray structure analyses of 1 and 2 reveal...

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Bibliographic Details
Main Authors: Ahmad Syed Usman, Beckmann Jens
Format: Article
Language:English
Published: De Gruyter 2012-05-01
Series:Main Group Metal Chemistry
Subjects:
Online Access:https://doi.org/10.1515/mgmc-2012-0003