A General Phenomenon of Spontaneous Amplification of Optical Purity under Achiral Chromatographic Conditions

A General Phenomenon of Spontaneous Amplification of Optical Purity under Achiral Chromatographic Conditions

This work explores the behavior of chiral compound mixtures enriched in one of the enantiomers whilst a typical chromatography on the achiral stationary phase is employed. The influence of several factors, such as the eluent composition, ratio of the compound to the stationary phase, and the initial...

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Bibliographic Details
Main Authors: K. Michał Pietrusiewicz, Mariusz Borkowski, Dorota Strzelecka, Katarzyna Kielar, Wioleta Kicińska, Sergei Karevych, Radomir Jasiński, Oleg M. Demchuk
Format: Article
Language:English
Published: MDPI AG 2019-05-01
Series:Symmetry
Subjects:
enantiomer self-disproportionation
SDE
achiral stationary phase
homochiral and heterochiral aggregates
chiral separation
chirality
genesis of life chirality
Online Access:https://www.mdpi.com/2073-8994/11/5/680

Internet

https://www.mdpi.com/2073-8994/11/5/680

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