Cyanidotetrakis(trimethylphosphine)cobalt(I)

The title compound, [Co(CN)(C3H9P)4], was obtained as a product of the reaction of [Co(PMe3)4] with a molar equivalent of 2,6-difluorobenzonitrile in diethyl ether. This compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The cobalt(I) atom has s...

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Bibliographic Details
Main Authors: Xiaofeng Xu, Lei Feng, Xiaoyan Li
Format: Article
Language:English
Published: International Union of Crystallography 2011-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681101083X