Cyanidotetrakis(trimethylphosphine)cobalt(I)

Cyanidotetrakis(trimethylphosphine)cobalt(I)

The title compound, [Co(CN)(C3H9P)4], was obtained as a product of the reaction of [Co(PMe3)4] with a molar equivalent of 2,6-difluorobenzonitrile in diethyl ether. This compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The cobalt(I) atom has s...

Full description

Bibliographic Details
Main Authors: Xiaofeng Xu, Lei Feng, Xiaoyan Li
Format: Article
Language:English
Published: International Union of Crystallography 2011-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681101083X
id doaj-44c2fbb83a454de4980e30b2dfdb7de2
record_format Article
spelling doaj-44c2fbb83a454de4980e30b2dfdb7de22020-11-25T02:14:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-04-01674m503m50310.1107/S160053681101083XCyanidotetrakis(trimethylphosphine)cobalt(I)Xiaofeng XuLei FengXiaoyan LiThe title compound, [Co(CN)(C3H9P)4], was obtained as a product of the reaction of [Co(PMe3)4] with a molar equivalent of 2,6-difluorobenzonitrile in diethyl ether. This compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The cobalt(I) atom has s trigonal–bipyramidal coordination enviroment in which the cyano group and one of the PMe3 groups are in the axial positions. http://scripts.iucr.org/cgi-bin/paper?S160053681101083X
collection DOAJ
language English
format Article
sources DOAJ
author Xiaofeng Xu
Lei Feng
Xiaoyan Li
spellingShingle Xiaofeng Xu
Lei Feng
Xiaoyan Li
Cyanidotetrakis(trimethylphosphine)cobalt(I)
Acta Crystallographica Section E
author_facet Xiaofeng Xu
Lei Feng
Xiaoyan Li
author_sort Xiaofeng Xu
title Cyanidotetrakis(trimethylphosphine)cobalt(I)
title_short Cyanidotetrakis(trimethylphosphine)cobalt(I)
title_full Cyanidotetrakis(trimethylphosphine)cobalt(I)
title_fullStr Cyanidotetrakis(trimethylphosphine)cobalt(I)
title_full_unstemmed Cyanidotetrakis(trimethylphosphine)cobalt(I)
title_sort cyanidotetrakis(trimethylphosphine)cobalt(i)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-04-01
description The title compound, [Co(CN)(C3H9P)4], was obtained as a product of the reaction of [Co(PMe3)4] with a molar equivalent of 2,6-difluorobenzonitrile in diethyl ether. This compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The cobalt(I) atom has s trigonal–bipyramidal coordination enviroment in which the cyano group and one of the PMe3 groups are in the axial positions.
url http://scripts.iucr.org/cgi-bin/paper?S160053681101083X
work_keys_str_mv AT xiaofengxu cyanidotetrakistrimethylphosphinecobalti
AT leifeng cyanidotetrakistrimethylphosphinecobalti
AT xiaoyanli cyanidotetrakistrimethylphosphinecobalti
_version_ 1724900240565207040

Similar Items