Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic dienes

Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic dienes

The Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic 1,3-dienes was investigated. A series of novel monofluorinated norbornenes was prepared in up to 97% yield. The reaction with 1,3-cyclohexadiene permits the preparation of monofluorinated bicyclo[2.2.2]oct-2-enes. The kinetic data of t...

Full description

Bibliographic Details
Main Authors: Savva A. Ponomarev, Roman V. Larkovich, Alexander S. Aldoshin, Andrey A. Tabolin, Sema L. Ioffe, Jonathan Groß, Till Opatz, Valentine G. Nenajdenko
Format: Article
Language:English
Published: Beilstein-Institut 2021-01-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
diels–alder reaction
fluorine
nitrostyrene
norbornene
stereochemistry
Online Access:https://doi.org/10.3762/bjoc.17.27

Internet

https://doi.org/10.3762/bjoc.17.27

Similar Items