Rearrangement of o-(pivaloylaminomethyl)benzaldehydes: an experimental and computational study

Rearrangement of o-(pivaloylaminomethyl)benzaldehydes: an experimental and computational study

Treatment of alkoxy-substituted o-(pivaloylaminomethyl)benzaldehydes under acidic conditions resulted in the formation of the regioisomeric aldehydes and/or dimer-like products. Detailed NMR studies and single-crystal X-ray measurements supported the structure elucidation of the compounds. DFT calcu...

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Bibliographic Details
Main Authors: Csilla Hargitai, Györgyi Koványi-Lax, Tamás Nagy, Péter Ábrányi-Balogh, András Dancsó, Gábor Tóth, Judit Halász, Angéla Pandur, Gyula Simig, Balázs Volk
Format: Article
Language:English
Published: Beilstein-Institut 2020-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
dft calculations
nmr
reaction mechanism
rearrangement
ring-chain tautomerism
Online Access:https://doi.org/10.3762/bjoc.16.136

Internet

https://doi.org/10.3762/bjoc.16.136

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