Synthesis and electrochemical characterization of bimetallic ruthenium complexes with the bridging h2(s,s)-1,3-butadiyne-1,4-diyl ligand
The bis(ruthenium)alkyne complex [cis-{RuCl (bpy)2(mu-C<FONT FACE="Symbol">º</FONT>C-)}]2 (1) was obtained by treatment of 1 equiv of either 1,4-bis(trimethylsilyl)-1,3-butadiyne or bis(trimetylsilyl)acetylene with 2 equiv of cis-[RuCl2(bpy)2].2H2O, NaF and NaBF4 salts in metha...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Sociedade Brasileira de Química
2000-01-01
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| Series: | Journal of the Brazilian Chemical Society |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300009 |