Synthesis and electrochemical characterization of bimetallic ruthenium complexes with the bridging h2(s,s)-1,3-butadiyne-1,4-diyl ligand

• Main Authors: Stein Edison, Oki Sergio Y., Vichi Eduardo J. S.
• Format: Article
• Language: English
• Published: Sociedade Brasileira de Química 2000-01-01
• Series: Journal of the Brazilian Chemical Society
• Subjects: electrochemistry; ruthenium complex; bimetallic complexes
• Online Access: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300009

The bis(ruthenium)alkyne complex [cis-{RuCl (bpy)2(mu-C<FONT FACE="Symbol">º</FONT>C-)}]2 (1) was obtained by treatment of 1 equiv of either 1,4-bis(trimethylsilyl)-1,3-butadiyne or bis(trimetylsilyl)acetylene with 2 equiv of cis-[RuCl2(bpy)2].2H2O, NaF and NaBF4 salts in methanol/CH2Cl2 mixture (10/1) in 52% and 35% yields, respectively. ¹H, 13C{H} NMR and principally electrochemical analyses confirmed that the same product was obtained from the two reactions. Cyclic voltammetric analyses of (1) from 0 to 1.20 V displays two one-electron quasi-reversible oxidation peaks attributed to the Ru(II)/Ru(III) couple. The redox processes are separated by 520 mV, indicating a significant electronic communication between the two metallic centers.