Crystal structure, electrochemical and spectroscopic investigation of mer-tris[2-(1H-imidazol-2-yl-κN3)pyrimidine-κN1]ruthenium(II) bis(hexafluoridophosphate) trihydrate

Crystal structure, electrochemical and spectroscopic investigation of mer-tris[2-(1H-imidazol-2-yl-κN3)pyrimidine-κN1]ruthenium(II) bis(hexafluoridophosphate) trihydrate

The crystal structure of the title compound, [Ru(C7H6N4)3](PF6)2·3H2O, a novel RuII complex with the bidentate ligand 2-(1H-imidazol-2-yl)pyrimidine, comprises a complex cation in the meridional form exclusively, with a distorted octahedral geometry about the ruthenium(II) cation. The Ru—N bonds inv...

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Bibliographic Details
Main Authors: Naheed Bibi, Renan Barrach Guerra, Luis Enrique Santa Cruz Huamaní, André Luiz Barboza Formiga
Format: Article
Language:English
Published: International Union of Crystallography 2018-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
homoleptic complex
heteroaryl-imidazole
ruthenium(II)
meridional isomer
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018007995

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http://scripts.iucr.org/cgi-bin/paper?S2056989018007995

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