Exchange interaction in short-lived flavine adenine dinucleotide biradical in aqueous solution revisited by CIDNP (chemically induced dynamic nuclear polarization) and nuclear magnetic relaxation dispersion

<p>Flavin adenine dinucleotide (FAD) is an important cofactor in many light-sensitive enzymes. The role of the adenine moiety of FAD in light-induced electron transfer was obscured, because it involves an adenine radical, which is short-lived with a weak chromophore. However, an intramolecular...

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Bibliographic Details
Main Authors: I. V. Zhukov, A. S. Kiryutin, M. S. Panov, N. N. Fishman, O. B. Morozova, N. N. Lukzen, K. L. Ivanov, H.-M. Vieth, R. Z. Sagdeev, A. V. Yurkovskaya
Format: Article
Language:English
Published: Copernicus Publications 2021-04-01
Series:Magnetic Resonance
Online Access:https://mr.copernicus.org/articles/2/139/2021/mr-2-139-2021.pdf