Synthesis and characterization of GeH2Cp*2 and its structural comparison with SiXHCp*2(X=Cl, H) and SnCl2Cp*2

The organogermane GeH2Cp*2 (1) was synthesized by the reaction of GeCl2Cp*2 (A) with LiAlH4 in quantitative yield, whereas the synthesis of the previously reported compounds SiCl2Cp*2 (B), SnCl2Cp*2 (C), SiClHCp*2 (D) and SiH2Cp*2 (E) followed established routes. The molecular structures of the Cp*M...

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Bibliographic Details
Main Authors: Fritzsche Ronny, Rüffer Tobias, Lang Heinrich, Mehring Michael
Format: Article
Language:English
Published: De Gruyter 2017-04-01
Series:Main Group Metal Chemistry
Subjects:
tin
Online Access:https://doi.org/10.1515/mgmc-2017-0014