Solid State Structure and Solution Thermodynamics of Three-Centered Hydrogen Bonds (O∙∙∙H∙∙∙O) Using N-(2-Benzoyl-phenyl) Oxalyl Derivatives as Model Compounds

Solid State Structure and Solution Thermodynamics of Three-Centered Hydrogen Bonds (O∙∙∙H∙∙∙O) Using N-(2-Benzoyl-phenyl) Oxalyl Derivatives as Model Compounds

Intramolecular hydrogen bond (HB) formation was analyzed in the model compounds N-(2-benzoylphenyl)acetamide, N-(2-benzoylphenyl)oxalamate and N1,N2-bis(2-benzoylphenyl)oxalamide. The formation of three-center hydrogen bonds in oxalyl derivatives was demonstrated in the solid state by the X-ray dif...

Full description

Bibliographic Details
Main Authors: Carlos Z. Gómez-Castro, Itzia I. Padilla-Martínez, Efrén V. García-Báez, José L. Castrejón-Flores, Ana L. Peraza-Campos, Francisco J. Martínez-Martínez
Format: Article
Language:English
Published: MDPI AG 2014-09-01
Series:Molecules
Subjects:
three-center hydrogen bond
oxalamide
oxalamate
steric effect
solvent effect
proton mobility
cooperativity
Online Access:http://www.mdpi.com/1420-3049/19/9/14446

Internet

http://www.mdpi.com/1420-3049/19/9/14446

Similar Items