Bias‐Polarity‐Dependent Direct and Inverted Marcus Charge Transport Affecting Rectification in a Redox‐Active Molecular Junction

Bias‐Polarity‐Dependent Direct and Inverted Marcus Charge Transport Affecting Rectification in a Redox‐Active Molecular Junction

Abstract This paper describes the transition from the normal to inverted Marcus region in solid‐state tunnel junctions consisting of self‐assembled monolayers of benzotetrathiafulvalene (BTTF), and how this transition determines the performance of a molecular diode. Temperature‐dependent normalized...

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Bibliographic Details
Main Authors: Yingmei Han, Cameron Nickle, Maria Serena Maglione, Senthil Kumar Karuppannan, Javier Casado‐Montenegro, Dong‐Chen Qi, Xiaoping Chen, Anton Tadich, Bruce Cowie, Marta Mas‐Torrent, Concepció Rovira, Jérôme Cornil, Jaume Veciana, Enrique del Barco, Christian A. Nijhuis
Format: Article
Language:English
Published: Wiley 2021-07-01
Series:Advanced Science
Subjects:
charge transport
inverted Marcus region
molecular diodes
molecular tunnel junctions
self‐assembly
Online Access:https://doi.org/10.1002/advs.202100055

Internet

https://doi.org/10.1002/advs.202100055

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