Synthesis, Structure and 1,3-Butadiene Polymerization Behavior of Vanadium(III) Phosphine Complexes

A series of vanadium(III) complexes bearing monodentate tertiary phosphine ligands of the type VCl3(PRnPh3-n)2 (n = 0 (1a); n = 1 and R = Me (1b), Et (1c), iPr (1d), Cy (1e); n = 2 and R = Me (1f), Et (1g), Cy (1h)), and VCl3(PR3)2 (R = Cyp (2a), Cy (2b), nPr (2c), tBu (2d)) were synthesized and cha...

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Bibliographic Details
Main Authors: Giuseppe Leone, Giorgia Zanchin, Ivana Pierro, Anna Sommazzi, Alessandra Forni, Giovanni Ricci
Format: Article
Language:English
Published: MDPI AG 2017-11-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/7/12/369