Condensation of Counterions Gives Rise to Contraction Transitions in a One-Dimensional Polyelectrolyte Gel

The equilibrium volume of a polyelectrolyte gel results from a balance between the tendency to swell caused by outbound polymer/counterion diffusion along with Coulomb interactions on the one hand; and, on the other, the elastic resilience of the cross-linked polymer network. Direct Coulomb forces c...

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Bibliographic Details
Main Author: Gerald S. Manning
Format: Article
Language:English
Published: MDPI AG 2018-04-01
Series:Polymers
Subjects:
Online Access:http://www.mdpi.com/2073-4360/10/4/432