The use of copper reagents on the base of copper (I) chloride for the synthesis of trans-3-substituted cyclic a-amino acids
An efficient synthesis of 3-substituted cyclic amino acids via 1,4-conjugate addition of diorganocuprates to α,β-unsaturated cyclic α-aminoacids is described.The higher reactivity of copper reagents obtained from copper (I) chloride in comparison with CuCN, CuBr, CuI and CuBr*SMe2 has been shown
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | Russian |
| Published: |
MIREA - Russian Technological University
2006-10-01
|
| Series: | Тонкие химические технологии |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/1445 |