Crystal structure of an eight-coordinate terbium(III) ion chelated by N,N′-bis(2-hydroxybenzyl)-N,N′-bis(pyridin-2-ylmethyl)ethylenediamine (bbpen2−) and nitrate

Crystal structure of an eight-coordinate terbium(III) ion chelated by N,N′-bis(2-hydroxybenzyl)-N,N′-bis(pyridin-2-ylmethyl)ethylenediamine (bbpen2−) and nitrate

The reaction of terbium(III) nitrate pentahydrate in acetonitrile with N,N′-bis(2-hydroxybenzyl)-N,N′-bis(pyridin-2-ylmethyl)ethylenediamine (H2bbpen), previously deprotonated with triethylamine, produced the mononuclear compound [N,N′-bis(2-oxidobenzyl-κO)-N,N′-bis(pyridin-2-ylmethyl-κN)ethylenedia...

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Bibliographic Details
Main Authors: Thaiane Gregório, André Luis Rüdiger, Giovana G. Nunes, Jaísa F. Soares, David L. Hughes
Format: Article
Language:English
Published: International Union of Crystallography 2015-01-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
lanthanide
terbium(III)
N,N′-bis(2-hydroxybenzyl)-N,N′-bis(pyridin-2-ylmethyl)ethylenediamine
mononuclear
dodecahedral.
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989014026826

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http://scripts.iucr.org/cgi-bin/paper?S2056989014026826

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