A binuclear vanadium oxyfluoride: di-μ-oxido-bis[fluoridooxido(1,10-phenanthroline)vanadium(V)]

The title compound, [V2F2O4(C12H8N2)2], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octahedral environment. The symmetry-equivalent VV atoms exhibit coordination geometries defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide gro...

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Bibliographic Details
Main Authors: Jon Zubieta, Paul DeBurgomaster
Format: Article
Language:English
Published: International Union of Crystallography 2010-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810037232