Crystal structure of μ-peroxido-κ4O1,O2:O1′,O2′-bis[(nitrato-κO)(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)dioxidouranium(VI)]

Crystal structure of μ-peroxido-κ4O1,O2:O1′,O2′-bis[(nitrato-κO)(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)dioxidouranium(VI)]

In the title dimeric complex, [{UO2(NO3)(C15H11N3)}2O2], a peroxide ion bridges the two uranyl(VI) [O=U=O]2+ ions. The O—O bond length of the peroxide is 1.485 (6) Å and the mid-point of this bond is located at the inversion centre of the dimer. The U atom exhibits a distorted hexagonal–bipyramidal...

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Bibliographic Details
Main Authors: Takeshi Kawasaki, Takafumi Kitazawa
Format: Article
Language:English
Published: International Union of Crystallography 2015-05-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
uranium(VI) complex
dimer
peroxide
2,2′:6′,2′′-terpyridine
uranyl(VI) ion
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015007987

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http://scripts.iucr.org/cgi-bin/paper?S2056989015007987

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