New Layered Oxide-Fluoride Perovskites: KNaNbOF5 and KNaMO2F4 (M = Mo6+, W6+)

KNaNbOF5 and KNaMO2F4 (M = Mo6+, W6+), three new layered oxide-fluoride perovskites with the general formula ABB’X6, form from the combination of a second-order Jahn-Teller d0 transition metal and an alkali metal (Na+) on the B-site. Alternating layers of cation vacancies and K+ cations on the A-sit...

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Bibliographic Details
Main Authors: Rachelle Ann F. Pinlac, Charlotte L. Stern, Kenneth R. Poeppelmeier
Format: Article
Language:English
Published: MDPI AG 2011-03-01
Series:Crystals
Subjects:
Online Access:http://www.mdpi.com/2073-4352/1/1/3