Synthesis and characterization of thiosemicarbazone derivatives of methylbismuth(III) dichloride: generation of one dimensional micro-rods of bismuthinite from [MeBiCl2·n{(C6H4OH)CHNNHCSNH2}] by a solvothermal process

Synthesis and characterization of thiosemicarbazone derivatives of methylbismuth(III) dichloride: generation of one dimensional micro-rods of bismuthinite from [MeBiCl2·n{(C6H4OH)CHNNHCSNH2}] by a solvothermal process

Reactions of methylbismuth(III) dichloride with thiosemicarbazones (TSC) in 1:1 and 1:2 molar ratios in anhydrous methanol yield [MeBiCl2.n{RR’CNNHCSNH2}] [where, R=R’=CH3 and n=1 (1) or n=2 (2); R=C6H4OH, R’=H and n=1 (3) or n=2 (4); R=C5H4N, R’=CH3 and n=1 (5) or n=2 (6)]. These monomeric adducts...

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Bibliographic Details
Main Authors: Yadav Neelam, Sharma Deepak, Nagar Meena, Bohra Rakesh
Format: Article
Language:English
Published: De Gruyter 2011-12-01
Series:Main Group Metal Chemistry
Subjects:
methylbismuth(iii) dichloride adducts
micro bi2s3
orthorhombic bismuthinite
Online Access:https://doi.org/10.1515/MGMC.2011.016

Internet

https://doi.org/10.1515/MGMC.2011.016

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