fac-Bromido/chlorido(0.50/0.50)[3-carbamoyl-1-(1,10-phenanthrolin-2-ylmethyl)pyridinium-κ2N,N′]tricarbonylmanganese(I) 0.49-bromide 0.51-chloride methanol monosolvate

fac-Bromido/chlorido(0.50/0.50)[3-carbamoyl-1-(1,10-phenanthrolin-2-ylmethyl)pyridinium-κ2N,N′]tricarbonylmanganese(I) 0.49-bromide 0.51-chloride methanol monosolvate

The title complex, [MnBr0.50Cl0.50(C19H15N4O)(CO)3]Br0.49Cl0.51·CH3OH, exhibits substitutional disorder of the halogen ligand in the asymmetric unit, with almost the same occupancies for Br and Cl. The MnI atom is coordinated in a distorted octahedral environment by three carbonyl C atoms, the disor...

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Bibliographic Details
Main Authors: Kosei Wadayama, Tsugiko Takase, Dai Oyama
Format: Article
Language:English
Published: International Union of Crystallography 2019-01-01
Series:IUCrData
Subjects:
crystal structure
manganese complex
phenanthroline derivative
substitutional disorder
NAD-mimic ligand
carbonyl
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314618017923

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http://scripts.iucr.org/cgi-bin/paper?S2414314618017923

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