Mechanistic Implications for the Ni(I)-Catalyzed Kumada Cross-Coupling Reaction

Mechanistic Implications for the Ni(I)-Catalyzed Kumada Cross-Coupling Reaction

Herein we report on the cross-coupling reaction of phenylmagnesium bromide with aryl halides using the well-defined tetrahedral Ni(I) complex, [(Triphos)NiICl] (Triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane). In the presence of 0.5 mol % [(Triphos)NiICl], good to excellent yields (75–97%) of t...

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Bibliographic Details
Main Authors: Linda Iffland, Anette Petuker, Maurice van Gastel, Ulf-Peter Apfel
Format: Article
Language:English
Published: MDPI AG 2017-11-01
Series:Inorganics
Subjects:
nickel
tripodal ligands
cross-coupling
EPR
Grignard
DFT
Online Access:https://www.mdpi.com/2304-6740/5/4/78

Internet

https://www.mdpi.com/2304-6740/5/4/78

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