Rhodium-Biphephos-Catalyzed Tandem Isomerization–Hydroformylation of Oleonitrile

Rhodium-Biphephos-Catalyzed Tandem Isomerization–Hydroformylation of Oleonitrile

Tandem isomerization–hydroformylation of oleonitrile (an 18-carbon nitrile with a remote internal (9-)C=C bond) has been studied using Rh-bisphosphite catalyst systems, targeting formation of the linear aldehyde. The best compromise between regioselectivity (l/b = 58:42) and chemoselectivity (60%) w...

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Bibliographic Details
Main Authors: Lucas Le Goanvic, Jérémy Ternel, Jean-Luc Couturier, Jean-Luc Dubois, Jean-François Carpentier
Format: Article
Language:English
Published: MDPI AG 2018-01-01
Series:Catalysts
Subjects:
tandem reaction
hydroformylation
isomerization
rhodium
Biphephos
oleonitrile
Online Access:http://www.mdpi.com/2073-4344/8/1/21

Internet

http://www.mdpi.com/2073-4344/8/1/21

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