Crystal structure of dimethyl-1κ2C-bis(μ-4-methylphenolato-1:2κ2O:O)(N,N,N′,N′-tetramethylethylenediamine-2κ2N,N′)indium(III)lithium(I)

Crystal structure of dimethyl-1κ2C-bis(μ-4-methylphenolato-1:2κ2O:O)(N,N,N′,N′-tetramethylethylenediamine-2κ2N,N′)indium(III)lithium(I)

The mixed bimetallic title compound, [InLi(CH3)2(C7H7O)2(C6H16N2)] or [(tmeda)Li-μ-(4-MeC6H4O)2InMe2] (tmeda is N,N,N′,N′-tetramethylethylenediamine), exhibits a four-membered LiO2In ring core via bridging 4-methylphenolate groups. The Li and In atoms are in distorted tetrahedral N2O2 and C2O2 bondi...

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Bibliographic Details
Main Authors: Glen G. Briand, Andreas Decken, Marshall R. Hoey
Format: Article
Language:English
Published: International Union of Crystallography 2015-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
bimetallic
indium
lithium
phenolate
spirocyclic
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015023476

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989015023476

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