Crystal structure of high-spin tetraaquabis(2-chloropyrazine-κN4)iron(II) bis(4-methylbenzenesulfonate)

Crystal structure of high-spin tetraaquabis(2-chloropyrazine-κN4)iron(II) bis(4-methylbenzenesulfonate)

The title salt, [FeII(C4H3ClN2)2(H2O)4](C7H7O3S)2, contains a complex cation with point group symmetry 2/m. The high-spin FeII cation is hexacoordinated by four symmetry-related water and two N-bound 2-chloropyrazine molecules in a trans arrangement, forming a distorted FeN2O4 octahedron. The three-...

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Bibliographic Details
Main Authors: Bohdan O. Golub, Sergii I. Shylin, Sebastian Dechert, Maria L. Malysheva, Il`ya A. Gural`skiy
Format: Article
Language:English
Published: International Union of Crystallography 2015-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
iron(II) complex
2-chloropyrazine
hydrogen bonding
π–π contacts
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015010713

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http://scripts.iucr.org/cgi-bin/paper?S2056989015010713

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