Chiral cyclopentadienylruthenium sulfoxide catalysts for asymmetric redox bicycloisomerization

A full account of our efforts toward an asymmetric redox bicycloisomerization reaction is presented in this article. Cyclopentadienylruthenium (CpRu) complexes containing tethered chiral sulfoxides were synthesized via an oxidative [3 + 2] cycloaddition reaction between an alkyne and an allylrutheni...

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Bibliographic Details
Main Authors: Barry M. Trost, Michael C. Ryan, Meera Rao
Format: Article
Language:English
Published: Beilstein-Institut 2016-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.12.110