Synthesis and characterization of a tert-butyl ester-substituted titanocene dichloride: t-BuOOCCp2TiCl2

Synthesis and characterization of a tert-butyl ester-substituted titanocene dichloride: t-BuOOCCp2TiCl2

Bis[η5-(tert-butoxycarbonyl)cyclopentadienyl]dichloridotitanium(IV), [Ti(C10H13O2)2Cl2], was synthesized from LiCpCOOt-Bu using TiCl4, and was characterized by single-crystal X-ray diffraction and 1H NMR spectroscopy. The distorted tetrahedral geometry about the central titanium atom is relatively u...

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Bibliographic Details
Main Authors: Jackson S. McCarthy, Colin D. McMillen, Jared A. Pienkos, Paul S. Wagenknecht
Format: Article
Language:English
Published: International Union of Crystallography 2020-10-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
titanocene
carboxylate anchoring group
metallocene
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989020011834

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http://scripts.iucr.org/cgi-bin/paper?S2056989020011834

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