Modulating NHC catalysis with fluorine

Fluorination often confers a range of advantages in modulating the conformation and reactivity of small molecule organocatalysts. By strategically introducing fluorine substituents, as part of a β-fluoroamine motif, in a triazolium pre-catalyst, it was possible to modulate the behaviour of the corre...

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Bibliographic Details
Main Authors: Yannick P. Rey, Ryan Gilmour
Format: Article
Language:English
Published: Beilstein-Institut 2013-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.9.316