Heterogenously catalyzed one-step alkylation and carboxylation of N-methylimidazole with dimethyl carbonate in continuous flow

The alkylation of N-methylimidazole with dimethyl carbonate yields the respective solid zwitterion N,N′-dimethylimidazolium-2-carboxylate, a versatile precursor for manufacturing non-halide-containing ionic liquids (ILs). This reaction requires high p,T-conditions, i.e., up to 200°C and 70 bar press...

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Bibliographic Details
Main Authors: Breuch Denis, Löwe Holger
Format: Article
Language:English
Published: De Gruyter 2012-06-01
Series:Green Processing and Synthesis
Subjects:
Online Access:https://doi.org/10.1515/gps-2012-0031