Ligand manipulation of charge transfer excited state relaxation and spin crossover in [Fe(2,2′-bipyridine)2(CN)2]

Ligand manipulation of charge transfer excited state relaxation and spin crossover in [Fe(2,2′-bipyridine)2(CN)2]

We have used femtosecond resolution UV-visible and Kβ x-ray emission spectroscopy to characterize the electronic excited state dynamics of [Fe(bpy)2(CN)2], where bpy=2,2′-bipyridine, initiated by metal-to-ligand charge transfer (MLCT) excitation. The excited-state absorption in the transient UV-visi...

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Bibliographic Details
Main Authors: Kasper S. Kjær, Wenkai Zhang, Roberto Alonso-Mori, Uwe Bergmann, Matthieu Chollet, Ryan G. Hadt, Robert W. Hartsock, Tobias Harlang, Thomas Kroll, Katharina Kubiček, Henrik T. Lemke, Huiyang W. Liang, Yizhu Liu, Martin M. Nielsen, Joseph S. Robinson, Edward I. Solomon, Dimosthenis Sokaras, Tim B. van Driel, Tsu-Chien Weng, Diling Zhu, Petter Persson, Kenneth Wärnmark, Villy Sundström, Kelly J. Gaffney
Format: Article
Language:English
Published: AIP Publishing LLC and ACA 2017-07-01
Series:Structural Dynamics
Online Access:http://dx.doi.org/10.1063/1.4985017

Internet

http://dx.doi.org/10.1063/1.4985017

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