Asymmetric Catalytic Ketimine Mannich Reactions and Related Transformations

Asymmetric Catalytic Ketimine Mannich Reactions and Related Transformations

The catalytic enantioselective ketimine Mannich and its related reactions provide direct access to chiral building blocks bearing an α-tertiary amine stereogenic center, a ubiquitous structural motif in nature. Although ketimines are often viewed as challenging electrophiles, various approaches/stra...

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Bibliographic Details
Main Authors: Changgong Xu, Carlyn Reep, Jamielyn Jarvis, Brandon Naumann, Burjor Captain, Norito Takenaka
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Catalysts
Subjects:
ketimine Mannich
ketimine allylation
aza-Morita–Baylis–Hillman
asymmetric catalysis
α-tertiary amine
β-amino carbonyl
Online Access:https://www.mdpi.com/2073-4344/11/6/712

Internet

https://www.mdpi.com/2073-4344/11/6/712

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