Cleavage of the Pt-I bond in a Primary Cycloplatinated Amine by Chelation

In the square-planar cycloplatinated complex of R–phenylethylamine, both additional substituents, an anionic iodo and a neutral donor ligand, have been replaced by chelating ethylenediamine. A very pronounced trans influence is observed in the cationic product complex: Two significantly different bo...

Full description

Bibliographic Details
Main Authors: William Raven, Irmgard Kalf, Ulli Englert
Format: Article
Language:English
Published: MDPI AG 2015-05-01
Series:Crystals
Subjects:
Online Access:http://www.mdpi.com/2073-4352/5/2/244