Saddle-shaped tetraphenylenes with peripheral gallic esters displaying columnar mesophases

Tetraphenylenes 2 with eight peripheral gallic esters were prepared in two steps from octamethoxytetraphenylene 1 in 19–72% yield. Investigation of the mesomorphic properties of 2 by DSC, POM and X-ray diffraction revealed that derivatives 2a–d with short alkoxy chain lengths (C5–C8) did not show an...

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Bibliographic Details
Main Authors: Eugen Wuckert, Constanze Hägele, Frank Giesselmann, Angelika Baro, Sabine Laschat
Format: Article
Language:English
Published: Beilstein-Institut 2009-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.5.57