Saddle-shaped tetraphenylenes with peripheral gallic esters displaying columnar mesophases
Tetraphenylenes 2 with eight peripheral gallic esters were prepared in two steps from octamethoxytetraphenylene 1 in 19–72% yield. Investigation of the mesomorphic properties of 2 by DSC, POM and X-ray diffraction revealed that derivatives 2a–d with short alkoxy chain lengths (C5–C8) did not show an...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Beilstein-Institut
2009-10-01
|
Series: | Beilstein Journal of Organic Chemistry |
Subjects: | |
Online Access: | https://doi.org/10.3762/bjoc.5.57 |