Bimetallic Aluminum 5,6-Dihydro-7,7-dimethyl quinolin-8-olates as Pro-Initiators for the ROP of ε-CL; Probing the Nuclearity of the Active Initiator

Bimetallic Aluminum 5,6-Dihydro-7,7-dimethyl quinolin-8-olates as Pro-Initiators for the ROP of ε-CL; Probing the Nuclearity of the Active Initiator

Six examples of aluminum 5,6-dihydro-7,7-dimethylquinolin-8-olates, [{2-R1-7,7-Me2-8-R2C9H6N-8-O}AlR32]2 (R1 = R2 = H, R3 = Me C1; R1 = R2 = H, R3 = Et C2; R1 = R2 = H, R3 = i-Bu C3; R1 = Cl, R2 = H, R3 = Me C4; R1 = H, R2 = R3 = Me C5; R1 = Cl, R2 = R3 = Me C6), have been prepared by treating the c...

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Bibliographic Details
Main Authors: Qiurui Zhang, Wenjuan Zhang, Gregory A. Solan, Tongling Liang, Wen-Hua Sun
Format: Article
Language:English
Published: MDPI AG 2018-07-01
Series:Polymers
Subjects:
aluminum complexes
ring opening polymerization
ε-caprolactone
bidentate
reaction mechanism
Online Access:http://www.mdpi.com/2073-4360/10/7/764

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http://www.mdpi.com/2073-4360/10/7/764

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